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41.
This paper reports an investigation on the structure-properties correlation of trivalent metal oxide (Al2O3)-doped V2O5 ceramics synthesized by the melt-quench technique. XRD patterns confirmed a single orthorhombic V2O5 phase formation with increasing strain on the doping of Al2O3 in place of V2O5 in the samples estimated by Williamson-Hall analysis. FTIR and Raman investigations revealed a structural change as [VO5] polyhedra converts into [VO4] polyhedra on the doping of Al2O3 into V2O5. The optical band gap was found in a wide semiconductor range as confirmed by UV–visible spectroscopy analysis. The thermal and conductivity behavior of the prepared samples were studied using thermal gravimetric analysis (TGA) and impedance analyzer, respectively. All the prepared ceramics exhibit good DC conductivity (0.22–0.36 Sm-1) at 400 ?C. These materials can be considered for intermediate temperature solid oxide fuel cell (IT-SOFC)/battery applications due to their good conductivity and good thermal stability. 相似文献
42.
《Ceramics International》2021,47(24):33978-33987
In this work, a novel and facile technique based on using KCl as space holders, along with partial sintering (at 1900 °C for 30 min), was explored to prepare porous ZrB2–SiC ceramics with controllable pore structure, tunable compressive strength and thermal conductivity. The as-prepared porous ZrB2–SiC samples possess high porosity of 45–67%, low average pore size of 3–7 μm, high compressive strength of 32–106 MPa, and low room temperature thermal conductivity of 13–34 W m−1 K−1. The porosity, pore structure, compressive strength and thermal conductivity of porous ZrB2–SiC ceramics can be tuned simply by changing KCl content and its particle size. The effect of porosity and pore structure on the thermal conductivity of as-prepared porous ZrB2–SiC ceramics was examined and found to be consistent with the classical model for porous materials. The poring mechanism of porous ZrB2–SiC samples via adding pore-forming agent combined with partial sintering was also preliminary illustrated. 相似文献
43.
44.
《Ceramics International》2022,48(20):29959-29966
High-purity SiC ceramic devices are applied in semiconductor industry owing to their outstanding properties. Nevertheless, it is difficult to densify SiC ceramics without any sintering additive even by HP sintering. In this work, high-purity and dense SiC ceramics were fabricated by HP sintering with very low amounts of sintering aids. Residual B content was only 556 ppm and relative density was more than 99.5%. Furthermore, thermal conductivity of as-prepared SiC ceramics was improved from 155 W m?1 K?1 to 167 W m?1 K?1 by increasing holding time and their plasma corrosion resistance was promoted in the meantime. The as-prepared high-purity SiC ceramics have broad application prospects in the field of semiconductor industry. 相似文献
45.
It is necessary to enhance the barrier performance of cutoff walls in order to improve the contamination control level, especially for reconstruction or expansion of existing landfill sites. This paper presents a comprehensive laboratory investigation on the synergistic effects of microorganisms and fibers on the hydraulic conductivity of silty sand to evaluate the applicability to the field condition as an alterative barrier material. Inside the soil, the added carbon fibers not only provided good biocompatibility, but also formed spatial three-dimensional network between soil particles to improve the bacterial adhesion that eventually caused 2–3 orders of magnitude decrease in soil permeability. The resistance of the biofilm to extreme conditions was tested by permeation with solutions of different salinity and pH values, and by subjecting specimens to various hydraulic gradients and soil conditions. Despite the microbial growth inhibition occurred at these conditions, however, biofilm can largely remain intact and continue to reduce k, which due to the gradual adaptation of microorganisms to the extreme environment and the gradual recovery of their activity. Results of these tests demonstrate that biofilm treatment may be a feasible technology for creating waste containment barriers in soil. 相似文献
46.
Guoqiang Li He Yang Danying Zuo Jing Xu Hongwei Zhang 《International Journal of Hydrogen Energy》2021,46(24):13044-13049
Gel polymer electrolytes (GPEs) can avoid the electrolyte leakage risk of electrochemical double layer capacitors (EDLCs). But aqueous GPEs often suffer from narrow electrochemical windows. Herein, a series of deep eutectic solvent (DES)-based supramolecular GPEs are firstly developed for carbon-based EDLCs with wide voltage windows. The as-fabricated DES-based GPE shows an ionic conductivity of ~58 mS cm?1, which makes the stable voltage window of a carbon-based EDLC reach 2.4 V. The carbon-based EDLC exhibits a specific capacitance of 32.1 F g?1, an energy density of 24.6 Wh kg?1 and a capacitance retention of ~90% after 15,000 charge-discharge cycles. Moreover, when quinhydrone is added into the DES-based GPE, the specific capacitance and energy density of the corresponding EDLC can be further expanded to 60 F g?1 and 43.6 Wh kg?1, respectively. Therefore, our work may present a universal strategy to prepare novel supramolecular GPEs for high-performance EDLCs with wide voltage windows. 相似文献
47.
The influence of Newtonian heating/cooling in the presence of heat source/sink has been investigated on laminar free convective flow in a vertical annular permeable region. The mathematical model for the problem has been considered as a boundary value problem consisting of two simultaneous ordinary differential equations. The boundary value problem has been transformed to nondimensional form. This has given rise to a number of parameters representing both geometrical and physical features of the problem. Closed‐form analytical solutions of the governing equations have been obtained for two different cases of internal heat generation/absorption. To assess the effects of governing parameters on the fluid velocity and temperature, a number of profiles of these field variables have been presented. The efficacy of the distinct processes on the field variables has been discussed extensively. The main outcome obtained in this study is that the velocity as well as temperature is enhanced in the case of the Newtonian heating while the opposite behavior occurs in the Newtonian cooling for both cases of source and sink. Furthermore, the influence of the governing parameters has been shown on the skin friction, volume flow rate, and the Nusselt number. 相似文献
48.
The numerical solutions of the upper-convected Maxwell (UCM) nanofluid flow under the magnetic field effects over an inclined stretching sheet has been worked out. This model has the tendency to elaborate on the characteristics of “relaxation time” for the fluid flow. Special consideration has been given to the impact of nonlinear velocity slip, thermal radiation and heat generation. To study the heat transfer, the modified Fourier and Fick's laws are incorporated in the modeling process. The mass transfer phenomenon is investigated under the effects of chemical reaction, Brownian motion and thermophoresis. With the aid of the similarity transformations, the governing equations in the ordinary differential form are determined and then solved through the MATLAB's package “bvp4c” numerically. This study also brings into the spotlight such crucial physical parameters, which are inevitable for describing the flow and heat transfer behavior. This has been done through graphs and tables with as much precision and exactitude as is possible. The ascending values of the magnetic parameter, the Maxwell parameter and the angle of the inclined stretching sheet cause decay in the dimensionless velocity while an assisting behavior of the thermal and concentration buoyancy parameters is noticed. 相似文献
49.
Farid Ahmed Md Atrehar Abir Muhtasim Fuad Farhana Akter Palash K. Bhowmik Syed Bahauddin Alam Dinesh Kumar 《亚洲传热研究》2021,50(5):5080-5105
50.
Khalil Ghanbari Ali Akbar Golneshan Mohsen Yazdani Hesam Moghadasi Navid Malekian 《亚洲传热研究》2021,50(6):5697-5713
Nanofluids have been known as practical materials to ameliorate heat transfer within diverse industrial systems. The current work presents an empirical study on forced convection effects of Al2O3–water nanofluid within an annulus tube. A laminar flow regime has been considered to perform the experiment in high Reynolds number range using several concentrations of nanofluid. Also, the boundary conditions include a constant uniform heat flux applied on the outer shell and an adiabatic condition to the inner tube. Nanofluid particle is visualized with transmission electron microscopy to figure out the nanofluid particles. Additionally, the pressure drop is obtained by measuring the inlet and outlet pressure with respect to the ambient condition. The experimental results showed that adding nanoparticles to the base fluid will increase the heat transfer coefficient (HTC) and average Nusselt number. In addition, by increasing viscosity effects at maximum Reynolds number of 1140 and increasing nanofluid concentration from 1% to 4% (maximum performance at 4%), HTC increases by 18%. 相似文献